Product ID:37875 AIRCRAFT WHITE ZENTHANE MIL-C-53039A #08620WUA-3Z
MSDS Date:04/28/1998
FSC:8010
NIIN:01-328-3233
Status Code:A
MSDS Number: CJHLJ

HENTZEN COATINGS, INC.

6937 WEST MILL ROAD
MILWAUKEE, WI 53218
US

Emergency Phone: 414-353-4200,DAY 800-424-9300,NITE

Info Phone: 414-353-4200

Preparer: JANE FREEMAN

Cage: 09225

HENTZEN COATINGS INC

18749 MILWAUKEE, WI 53218 US

Telephone: 414-353-4200

Cage: 09225

METHYL ISOBUTYL KETONE

CAS: 108-10-1

Fraction By Weight: 18.6600%

OSHA PEL 50 PPM

ACGIH TLV: 50 PPM

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 20-30%

OSHA PEL 10 MG/M3

ACGIH TLV: 10 MG/M3

SILICA, CRYSTALLINE

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 15-20%

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.1 MG/M3

XYLENE (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 1.5000%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

AROMATIC HYDROCARBONS (MIXTURE OF C8'S TO C10'S)

CAS: 64742-95-6

Fraction By Weight: 1.0690%

BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 1.0690%

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

HEXAMETHYLENE DIISOCYANATE MONOMER

CAS: 822-06-0

RTECS: MO1740000

Fraction By Weight: .0320%

OSHA PEL 0.005 PPM

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

HOMOPOLYMER OF HEXAMETHYLENE DIISOCYANATE

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 20-30%

METHYL ISOAMYL KETONE

CAS: 110-12-3

RTECS: MP3850000

Fraction By Weight: 7.3050%

OSHA PEL 50 PPM

ACGIH TLV: 50 PPM

Reports of Carcinogenicity:NTP:YES IARC:YES
Health Hazards Acute and
Chronic:ACUTE:EYES:IRRIT/TEARING/REDDENING/SWELLING/STINGING.IF
UNTREATED:CORNEAL DAMAGE/SLOW TO
HEAL.SKIN:IRRIT:REDDENING/RASH/SWELLING/SCALING/BLISTERING/POSSIBLE
SKIN SENSITIZATION.IF MATERIAL DRIES ON SKI N:REMOVAL VERY
DIFFICULT.REPEATED/PROLONGED SKIN CONTACT:POSSIBLE
DEFATTING/DERMATITIS.INHAL:ANESTHETIC.POSSIBLE RESP TRACT
IRRIT/ACUTE NERVOUS SYSTEM DEPRESSION SHOWN BY
HEADACHE/DIZZINESS/STAGGERING
/CONFUSION/UNCONSCIOUSNESS.ISOCYANATES IRRIT/BURN MUCOUS MEMBRANE
IN RESP TRACT(NOSE/THROAT/LUNGS):RUNNY NOSE/SOAR
THROAT/COUGHING/CHEST DISCOMFORT/SHORTENED BREATH/REDUCED LUNG
FUNCTION/BREATHING OBS TRUCTION.*CONTINUED UNDER SIGNS/SYMPTOMS
Explanation of Carcinogenicity:IARCH LISTS CRYSTALINE SILICA:GROUP
1,CARCENOGENIC TO HUMANS.NTP CLASSIFIES CRYSTALINE SILICA AS
REASONABLY ANTICIPATED TO BE CARCINOGEN:MAY CAUSE LUNG INJURY IF
RESP PRECAUTIONS ARE NOT USED.
Effects of Overexposure:CONTINUED HEALTH HAZ:INHAL:POSSIBLE ASTHMA-LIKE
SYMPTOMS/ASTHMA ATTACK.POSSIBLE BRONCITIS/BRONCHIAL SPASM/PULMONARY
EDEMA.THESE EFFECTS USUALLY REVERSABLE.POSSIBLE CHEMICAL
PNEUMONITIS W/FLU-LIKE SYMP TOMS(FEVER/CHILLS).POSSIBLE THROAT
DRYNESS/CHEST TIGHTNESS/HEADACHE/NAUSEA/FATIGUE/APPETITE
LOSS.INGEST:IRRIT/POSSIBLE CORROSIVE ACTION:MOUTH/STOMACH
TISSUE/DIGEST TRACT.SYMPTOMS:SOAR THROAT/ABDOMONAL
PAIN/NAUSEA/VOMITING/DIARRHEA.VOMITING CAUSE POSSIBLE ASPIRATION OF
SOLVENT INTO LUNGS LEADING TO CHEMICAL PNEUMONITITS. **CONTINUED
UNDER TOXICOLOGICAL SECTION (SIGN&SYMPTOMS LISTED BELOW UNDER MED
COND AGGRAVATED)
Medical Cond Aggravated by Exposure:ASTHMA/OTHER RESP AILMENTS.SKIN
ALERGIES/EXEMA.CHEM SENSTZATION.SIGNS&SYMPTOMS:HARMFUL IF
INHALED.EFFECTS:NOSE,THROAT,RESP TRACT IRRIT,ALERGIC RESP
REACTION,LUNG DAMAGE,EYE&SKIN IRRIT,SKIN REACTIONS.

First Aid:EYES: FLUSH IMMED WI/LOW PRESSURE LUKE WARM WATER FOR 15
MINUTES, LIFTING LIDS TO RINSE ENTIRE EYE. TAKE TO DR IMMED.SKIN:
REMOVE CONTAMINATED CLOTHING IMMED & WASH THOROUGHLY BEFORE REUSE.
WASH EFFEC TED AREAS THOROUGHLY W/SOAP/WATER. SEVERE EXPOSURE:GET
UNDER SAFETY SHOWER AFTER REMOVING CLOTHING. CALL DR IN BOTH
CASES.INHAL:REMOVE TO RISK FREE AREA.ADMINISTER OXYGEN/ARTIFICIAL
RESP AS NEEDED. GE T DR. POSSIBLE ASTHMIATIC TYPE SYMPTOMS IMMED OR
SEVERAL HOURS LATER. SEE DR. INGEST:CALL DR IMMED! DO NOT INDUCE
VOMITING.

Flash Point:=15.6C, 60.F
Lower Limits:1.0
Upper Limits:8.20
Extinguishing Media:FOAM, DRY CHEMICAL AND CO2 OR ALCOHOL FOAM
Fire Fighting Procedures:FULL PROTECT EQUIP W/ SELF-CONTAINED BREATHING
APPARATUS SHOULD BE WORN.DURING FIRE, IRRIT & HIGHLY TOXIC GASES &
SMOKE ARE PRESENT FROM DECOMP/COMBUST PRODS.KEEP CONTRS TIGHTLY
CLOSED.ISOLATE FROM HE AT/ELECTRICAL EQUIP/SPARKS/OPEN FLAMES.
Unusual Fire/Explosion Hazard:CLOSED CONTRS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT OR BURST WHEN CONTAM W/ H2O (CO2 RELEASED).DO NOT
APPLY TO HOT SURFACES.NEVER USE WELDING/CUTTING TORCH ON/NEAR
CONTRS(EVEN EMPTY) B/C PRODUCT(EV EN RESIDUE) CAN IGNITE
EXPLOSIVELY.FLAMMABLE LIQUID!KEEP AWAY FROM
HEAT/SPARKS/FLAME.VAPORS MAY CAUSE FLASH FIRE.

Spill Release Procedures:EVAC NON-ESSENTIAL PERSONNEL.REMOVE ALL IGNIT
SOURCES:FLAMES/HOT SURFACES/ELECTRICAL/STATIC & FRICTIONAL
SPARKS.VENTILATE AREA.EQUIP CLEAN UP CREW W/APRROP PROTECTIVE
EQUIP.AVOID BREATH VAPORS/SKIN CO NTACT.COVER SPILL W/INERT
ABSORBENT.POUR LIQUID DECONTAM OVER SPILL:LET STAND 10 MIN.COLLECT
MATERIAL IN OPEN CONTNRS/ADD FURTHER AMOUNTS DECONTAM
SOLUTION.***CONT UNDER ECOLOGICAL SECTION
Neutralizing Agent:CONCENTRTD AMONIA(3-8%),DETERGENT(2%)&H2O(90-95%).OR
SOLUTION OF NIACT CORP'S TERGITOL TMN-10(20%) & H2O(80%).

Handling and Storage Precautions:PROTECT PERSONS HANDLING PRODUCT:MUST
NOT BREATHE VAPORS/CONTACT EYES/SKIN. IN SPRAY
OPERATIONS:PROTECTION AFFORDED AGAINST EXPOSURE TO VAPOR/SPRAY
MIST.CAN CAUSE IRRIT TO EYES/SKIN/NOSE/THROAT.AVOID EYES/CLOTHING
CONTACT.WASH THOROUGHLY AFTER HANDLING. AVOID PROLONGED/REPEATED
CONTACT W/SKIN.
Other Precautions:USE GROUNDING/BONDING CONNECTIONS IN TRANFERING
MATERIAL TO PREVENT STATIC DISCHARGE/FIRE OR EXPLOSION.AVOID LIQUID
FREE-FALL>FEW INCHES.USE SPARK PROOF TOOLS/EXPLOSION PROOF
EQUIP.DON'T STORE ABOVE 1 20F OR BELOW 32 F.STORE LG QUANTITIES IN
BUILDINGS THAT COMPLY W/OSHA'S 29 CFR 1910.106. ****CONT UN DER
ECOLOGICAL

Respiratory Protection:AIRLINE RESPIRATORS UNLESS AIR SAMPLING SHOWS
EXPOSURE TO BE BELOW OSHA LIMITS. THEN, EITHER CHEMICAL CARTRIDGE
RESPIRATORS OR AIRLINE RESPIRATORS ARE REQUIRED.USE SAME
PRECAUTIONS DURING MIXING OR WH ERE PAINT FUMES WOULD BE PRESENT.
*****CONTINUED UNDER OTHER INFORMATION SECTION
Ventilation:EXHAUST TO KEEP AIRBORN CONTAMS BELOW EXPOSURE LIMITS.CLEAN
EXHAUST AIR BY SCRUBBER/FILTERS.VENT CURING OVENS.IF OVEN OFF,GASES
NOT VENTED PROPERLY
Protective Gloves:PERMIATION RESISTANT GLOVES
Eye Protection:SAFETY EYE WEAR W/SPLASH GUARDS OR SIDE SHIELDS.FACE
SHIELD.NO CONTACT LENSES.
Other Protective Equipment:WEAR PROTECTIVE CLOTHING TO KEEP SKIN
CONTACT AT A MINIMUM.KEEP SKIN CREAM PROTECTED AREAS TO A
MINIMUM.SAFETY SHOWERS/EYE WASH STATIONS.TRAIN EMPLOYEES IN SAFE
USE OF THIS PRODUCT.
Work Hygienic Practices:ONCE A PERSON IS SENSITIZED TO ISOCYANATES, NO
FURTHER EXPOSURE CAN BE PERMITTED.
Supplemental Safety and Health
MEDICAL SUPERVISION OF ALL EMPLOYEES HANDLING THIS PRODUCT
RECOMMENDED.SHOULD INCLUDE PRE-EMPLOYMENT & PERIODIC MEDICAL EXAMS
W/ RESP FUNCTION TESTS(FEV, FVC MINIMUM).PERSONS W/ASTHMA-TYPE
CONDITIONS/ BRONCHITIS/OTHER RESP DISEASES OR RECURRENT SKIN
EXEMA/SENSITIZATION SHOULD BE EXCLUDED FROM WORKING W/ISOCYANATES.

Boiling Pt:B.P. Text:232 F TO 418 F
Vapor Pres:15
Vapor Density:4.800
Spec Gravity:1.3600
VOC Grams/Liter:3.38
Evaporation Rate & Reference:1.6000 (N-BU AC=1)
Solubility in Water:REACTS WITH WATER
Appearance and Odor:OPAQUE LIQUID, SOLVENT ODOR
Percent Volatiles by Volume:49.830

Stability Indicator/Materials to Avoid:YES
WATER/MOISTURE,EPOXY CATALYSTS,ALCOHOLS,GLYCOL ETHERS,BASES,METAL
COMPLEXES,OR OTHER ACTIVE MATERIALS.
Stability Condition to Avoid:ONCE PRODUCT IS EXPOSED TO ANY MATERIALS
LISTED BELOW (INCLUD ATMOSPHERIC MOISTURE), DO NOT RESEAL CONTR AS
HAZ CO2 GAS COULD BUILD UP IN CONTR RESULTING IN RAPID
DEPRESSURIZATION.
Hazardous Decomposition Products:MAY PRODUCE HAZ FUMES WHEN HEATED TO
DECOMP POINT(AS IN WELDING). FUMES MAY CONTAIN:CO2, CO,
CHLORINE,HYDROGEN CHLORIDE & POSSIBLE CYANIDE, HEXAMETHYLENE
DIISOCYANATE.

Waste Disposal Methods:RECYCLE,FUEL BLEND,OR INCINERATE.DISPOSE OF IN
ACCORDANCE W/ LOCAL/STATE/FED ENVIRONMENTAL CONTROL
REGULATIONS.DISPOSE OF PROPERLY.PROFILE WASTE W/ LAB ANALYSIS FOR
PROPER DISPOSAL. DECONTAMINATE CONT AINERS W/ DECONTAM SOLUTION. US
EPA WASTE # & DESCRIPTION: D001 WASTE PAINT. HAZ WASTE:IGNITIBLE.

Toxicological Information:*CONT HEALTH HAZ CHRONIC EFFECTS:POSSIBLE
PERMANENT BRAIN,NERVOUS SYSTEM,LUNG,LIVER&KIDNEY DAMAGE.CERTAIN
PERSONS DEVELOP ISOCYANATE SENSITIZATION(CHEMICAL ASTHMA)CAUSING
REACTIONS TO LATER EXPOSURE W ELLTO SEVERAL HOURS AFTER EXPSRE.INCLUDES:CHEST
TIGHTNESS,WHEEZING,COUGH,ASTHMATIC ATTACK.ONCE SENSITIZED,PERSON
CAN HAVE THESE SYMPTOMS EXPOSED TO DUST/COLD AIR/OTHE R
IRRITANTS.CAN PERSIST FOR WEEKS/SOME CASES-SEVERAL
YEARS.SENSIZATION TEMP OR PERMANENT.POSSIBLE SKIN
REDDENING,SWELLING,DERMATITIS.REPORTS LINK XYLENE TO HEARING LOSS.

======================================================================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:***CONT SPILL RELEASE:REMOVE CONTRS TO SAFE PLACE.COVER
LOOSELY.ALLOW TO STAND 24-48 HRS.WASH SPILL AREA W/DECONTAM
SOLUTION.DON'T ALLOW PRODUCT/USED DECONTAM SOLUTION TO ENTER
DRAINS,SEWERS,WATERWAYS . ****CONT STORAGE&HANDLING:KEEP AWAY FRM
HEAT/SPARKS/FLAME.KEEP CONTRS TIGHTLY CLOSED&PROTECT FRM MOISTURE
CONTAMINATION.IF MOISTURE ENTERS CONTR,PRESSURE CAN BUILD DUE TO
REACTION PRODUCING CO2, WHI CH CAUSES SEALED CONTR TO
PRESSURIZE&BURST.DON'T RESEAL CONTR IF CONTAM IS SUSPECTED.EMPTY
CONTRS RETAIN HAZ RESIDUE.FOLLOW HAZ PRECAUTIONS UNTIL CONTR
THOROUGHLY CLEANED/DESTROYED.SOAK SOILED RAGS&WA STE IMMED IN
H2OFILLED CLOSED CONTR.

Transport Information:*******CONTINUED FROM STATE REG SECTION:USE ONE
OR MORE OF FOLLOWING CONTROL PROCEDURES WHEN WELDING/CUTTING COATED
STEEL:USE POWER BRUSH,GRINDING WHEEL,OR CHEM STRIPPER TO REMOVE
COATING FROM STEEL I N THE AREA TO BE CUT OR WELDED.USE RESP/EYE
PROTECTION WHILE STRIPPING PAINT.USE LOCAL EXHAUST HOOD TO REMOVE
FUMES DURING WELDING/CUTTING OPERATION.WEAR A FRESH AIR SUPPLIED
RESPIRATOR DURING WELDING /CUTTING.

SARA Title III Information:HEXAMETHYLENE DIISOCYANATE MONOMER; XYLENE;
METHYL ISOBUTYL KETONE.
Federal Regulatory Information:CONT RESPIRATORY: A PROPERLY FITTED AIR
PURIFYING RESP(COMBO ORGANIC VAPOR/PARTICULATE), PROVEN BY TESTS TO
BE EFFECTIVE IN ISOCYANATE-CONTAINING SPRAY PAINT ENVIRONMENTS AND
USED IN ACCORD W/ ALL REC OMMENDATIONS MADE BY MANUFACTURER CAN BE
USED WHEN:1)AIRBORNE ISOCYANATE CONCENTRATIONS ARE KNOWN TO BE
BELOW TEN TIMES EXPOSURE LIMITS;2)AT LEAST ONE SOLVENT IN COATING
HAS PUBLISHED ODOR THRESHHOLD; AND 3)AIRBORNE SOLVENT IS LOWER THAN
ITS TLV BUT HIGHER THAN ITS ODOR THRESHHOLD.ODOR OF SOLVENT WIL L
THEN ALERT RESP WEARER TO ANY BREAKDOWN OF RESP FILTERS. CONT UNDER
STATE REG. SECTION
State Regulatory Information:CONT FROM FED REGS:SAME PRECAUTIONS APPLY
DURING NONSPRAY OPERATIONS SUCH AS BRUSH,ROLLER APPLICATION OF
COATING IF DONE AT ELEVATED TEMPS(HEATING COATING FOR
APPLICATION).DURING SANDING/GRINDING USIN G NIOSH APPROVED
PARTICULATE RESP TO REMOVE SOLID AIRBORNE PARTICLES OF DUST. WHEN
WELLDING/CUTTING STEEL COATED W/PRODUCT, WORKER MAY BE EXPOSED TO
DECOMP PRODUCTS(METAL FUMES,GASES,VAPORS,AND/OR PAR TICULATE)WHICH
VARY DEPENDING ON TYPE OF PROCESS BEING USED TO WELD/CUT AND NATURE
OF BASE METAL. ** ****CONTINUED UNDER TRANSPORTATION SECTION.